Recent Developments in Transition Metal-Catalyzed Polymerization I. Polymerization of Propylene by Silylene- and Germylene-Bridged Group 4 Metallocenes.
نویسندگان
چکیده
منابع مشابه
Testing DFT ability to predict the stereoselectivity of group 4 metallocenes in propylene polymerization
In this study we have tested the ability of a standard DFT computational protocol to reproduce the experimentally obtained stereoselectivity of 26 different C2-symmetric zirconocene catalysts active in propylene polymerization. The catalysts were chosen for their relevance in metallocene catalyzed polymerization of propylene. To this end, primary insertion of both si- and re-propylene enantiofa...
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This review article describes developments in chiral metallocenes as polymerization catalysts focusing on C2 symmetric ansa-zirconocene complexes. Selective synthesis of rac-isomers of ansa-zirconocenes are surveyed. Isospecific polymerizations of propylene catalyzed by chiral zirconocenes are summarized. Advanced series of polymerizations by chiral metallocenes such as asymmetric polymerizatio...
متن کاملtesting dft ability to predict the stereoselectivity of group 4 metallocenes in propylene polymerization
in this study we have tested the ability of a standard dft computational protocol to reproduce the experimentally obtained stereoselectivity of 26 different c2-symmetric zirconocene catalysts active in propylene polymerization. the catalysts were chosen for their relevance in metallocene catalyzed polymerization of propylene. to this end, primary insertion of both si- and re-propylene enantiofa...
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The synthesis of a series of C1-symmetric metallocene complexes rac-[1-(5,6-dialkoxy-2-methyl1-η5-indenyl)-2-(9-η5-fluorenyl)ethane]zirconium dichlorides (alkyl: n-butyl, n-hexyl, n-octyl, ndecyl) is described. These complexes are versatile catalysts in the polymerization of propylene after in situ activation with triisobutylaluminum (TIBA) and Ph3C[B(C6F5)4] in toluene and heptane solution. Al...
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ژورنال
عنوان ژورنال: KOBUNSHI RONBUNSHU
سال: 2002
ISSN: 0386-2186,1881-5685
DOI: 10.1295/koron.59.243